Jornada 1
| 15 Nov 64 |  Tenerife |
2 - 2 |  Badalona |
... |
| 15 Nov 64 |  Mallorca |
2 - 0 |  Sabadell |
... |
| 15 Nov 64 |  CD Málaga |
0 - 1 |  Pontevedra |
... |
| 15 Nov 64 |  Real Unión |
4 - 0 |  Algeciras |
... |
| 15 Nov 64 |  Barakaldo |
4 - 1 |  Cádiz |
... |
| 15 Nov 64 |  Club |
3 - 2 |  Real |
... |
| 15 Nov 64 |  CD Abarán |
3 - 3 |  Racing |
... |
| 15 Nov 64 |  Puertollano |
2 - 1 |  CE Europa |
... |
| 15 Nov 64 |  Recreativo |
3 - 0 |  L´Hospital |
... |
| 15 Nov 64 |  Celta |
2 - 0 |  Hércules |
... |
| 15 Nov 64 |  Burgos |
5 - 0 |  UD Melilla |
... |
| 15 Nov 64 |  Real |
4 - 1 |  Real |
... |
| 15 Nov 64 |  Granada |
6 - 1 |  Langreo |
... |
| 15 Nov 64 |  CD Ourense |
1 - 3 |  Ontinyent |
... |
| 15 Nov 64 |  Osasuna |
2 - 1 |  Constància |
... |
| 14 Nov 64 |  Valencia |
5 - 1 |  Indautxu |
... |
Jornada 2
| 14 Mar 65 | Racing |
6 - 0 | CD Abarán |
... |
| 14 Mar 65 | Real |
4 - 0 | Club |
... |
| 14 Mar 65 | Cádiz |
2 - 0 | Barakaldo |
... |
| 14 Mar 65 | UD Melilla |
4 - 5 | Burgos |
... |
| 14 Mar 65 | CE Europa |
0 - 1 | Puertollano |
... |
| 14 Mar 65 | Badalona |
0 - 0 | Tenerife |
... |
| 14 Mar 65 | Hércules |
0 - 1 | Celta |
... |
| 14 Mar 65 | Langreo |
1 - 0 | Granada |
... |
| 14 Mar 65 | Pontevedra |
1 - 0 | CD Málaga |
... |
| 14 Mar 65 | Sabadell |
0 - 1 | Mallorca |
... |
| 14 Mar 65 | Indautxu |
1 - 1 | Valencia |
... |
| 14 Mar 65 | Ontinyent |
2 - 1 | CD Ourense |
... |
| 14 Mar 65 | Constància |
0 - 0 | Osasuna |
... |
| 14 Mar 65 | Algeciras |
1 - 0 | Real Unión |
... |
| 14 Mar 65 | Real |
2 - 4 | Real |
... |
| 14 Mar 65 | L´Hospital |
0 - 0 | Recreativo |
... |
Jornada 3
Jornada 4
Jornada 5
Espanyol
Sevilla
Elche
Real Oviedo
Real Betis
Jornada 6
| 30 May 65 |  Levante |
3 - 2 |  Real |
... |
| 30 May 65 |  Córdoba |
0 - 0 |  Valencia |
... |
| 30 May 65 | Real |
4 - 0 | Osasuna |
... |
| 30 May 65 | Pontevedra |
2 - 0 | Mallorca |
... |
| 30 May 65 |  Atlético |
4 - 0 |  Real Madrid |
1 |
| 30 May 65 | Real |
0 - 1 |  Deportivo |
... |
| 30 May 65 |  Real Murcia |
1 - 0 |  Barcelona |
... |
| 30 May 65 |  Las Palmas |
1 - 2 |  Athletic |
... |
| 23 May 65 | Mallorca |
0 - 0 | Pontevedra |
... |
| 23 May 65 | Barcelona |
4 - 1 | Real Murcia |
... |
| 23 May 65 | Athletic |
2 - 2 | Las Palmas |
... |
| 23 May 65 | Osasuna |
2 - 1 | Real |
... |
| 23 May 65 | Real Madrid |
1 - 0 | Atlético |
... |
| 23 May 65 | Real |
7 - 2 | Levante |
... |
| 23 May 65 | Deportivo |
0 - 2 | Real |
... |
| 22 May 65 | Valencia |
2 - 1 | Córdoba |
... |
Jornada 7
Jornada 8
Jornada 9
Athletic
Atlético
Barcelona
Celta
Espanyol
RC Deportivo
Real Betis
Real Madrid
Real Sociedad
Real Zaragoza
Sevilla
Valencia
Mallorca
Real Sporting
Cádiz
Recreativo
Real Murcia
Racing
Osasuna
Real Valladolid
Real Oviedo
Hércules
Granada
CE Sabadell
Elche
Levante
Barakaldo
Las Palmas
Real Unión Club
Tenerife
Córdoba CF
Burgos
Pontevedra
Badalona
CE Europa
CD Málaga
Algeciras CF
Valencia Mestalla
Constància
Langreo
L´Hospitalet
CD Ourense
UD Melilla
Ontinyent CF
Puertollano
SD Indautxu
CD Abarán
Club Atlético De Ceuta